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Mechanistic insight into aryl-nickel-catalyzed benzylic dehydrogenation of electron-deficient heteroarenes by using DFT calculations

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We recently investigated the mechanism of aryl-nickel-catalyzed benzylic dehydrogenation of electron-deficient heteroarenes by using DFT calculations, which is an elegant protocol for accessing important precursor compounds such as 2-alkenyl heteroarenes.... Click to show full abstract

We recently investigated the mechanism of aryl-nickel-catalyzed benzylic dehydrogenation of electron-deficient heteroarenes by using DFT calculations, which is an elegant protocol for accessing important precursor compounds such as 2-alkenyl heteroarenes....

Keywords: dehydrogenation electron; catalyzed benzylic; electron deficient; benzylic dehydrogenation; nickel catalyzed; aryl nickel

Journal Title: New Journal of Chemistry
Year Published: 2021

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