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Merging of cationic RAFT and radical RAFT polymerizations with ring-opening polymerizations for the synthesis of asymmetric ABCD type tetrablock copolymers in one pot

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A new bifunctional and switchable RAFT agent and a mechanism switching strategy were proposed to control the cationic RAFT polymerization, radical RAFT polymerization and ring-opening polymerization of vinyl and cyclic… Click to show full abstract

A new bifunctional and switchable RAFT agent and a mechanism switching strategy were proposed to control the cationic RAFT polymerization, radical RAFT polymerization and ring-opening polymerization of vinyl and cyclic ester monomers and to produce block copolymers.

Keywords: merging cationic; ring opening; cationic raft; raft; radical raft; raft radical

Journal Title: Polymer Chemistry
Year Published: 2021

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