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An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters

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By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11]… Click to show full abstract

By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11] FBBs and dimeric [Sb2O6] clusters.

Keywords: antimony iii; dimeric sb2o6; unwonted b5o11; iii borate; large birefringence; sb2o6 clusters

Journal Title: Inorganic chemistry frontiers
Year Published: 2021

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