By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11]… Click to show full abstract
By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11] FBBs and dimeric [Sb2O6] clusters.
               
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