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Probing the generality of spin crossover complex T½vs. ligand 15N NMR chemical shift correlations: towards predictable tuning

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A study of 6 families (42 members) demonstrates that within a family the easily calculated 15N-NMR values of ligands enable predictable tuning of T1/2 in the corresponding complexes, except for… Click to show full abstract

A study of 6 families (42 members) demonstrates that within a family the easily calculated 15N-NMR values of ligands enable predictable tuning of T1/2 in the corresponding complexes, except for 2 families with weakly influencing meta-substituents.

Keywords: predictable tuning; spin crossover; crossover complex; 15n nmr; generality spin; probing generality

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2021

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