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Visible-light-induced remote C(sp3)–H sulfonylvinylation: assembly of cyanoalkylated vinyl sulfones

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A photoinduced three-component sulfonylvinylation reaction of propargyl alcohols, potassium metabisulfite and cycloketone oxime esters is developed, affording cyanoalkylated vinyl sulfones in moderate to good yields. Click to show full abstract

A photoinduced three-component sulfonylvinylation reaction of propargyl alcohols, potassium metabisulfite and cycloketone oxime esters is developed, affording cyanoalkylated vinyl sulfones in moderate to good yields.

Keywords: light induced; visible light; induced remote; vinyl sulfones; cyanoalkylated vinyl; sulfonylvinylation

Journal Title: Organic Chemistry Frontiers
Year Published: 2021

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