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In an unusual cascade process involving KCN, vinyl cyclic carbonates are converted into β-cyano ketones with the subsequent extrusion of carbon dioxide and acetonitrile facilitating a Michael addition to an… Click to show full abstract
In an unusual cascade process involving KCN, vinyl cyclic carbonates are converted into β-cyano ketones with the subsequent extrusion of carbon dioxide and acetonitrile facilitating a Michael addition to an intermediate α,β-unsaturated ketone.
Keywords:
cyano ketones;
ketones cyanide;
formation cyano;
promoted ring;
cyanide promoted;
cyano
Journal Title: Organic Chemistry Frontiers
Year Published: 2021
Link to full text (if available)
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Journal Title: Organic Chemistry Frontiers
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!