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Controllable Z/E-selective synthesis of α-amino-ketoximes from N-nitrososulfonamides and aryl alkenes under neutral conditions

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An amidoximation of alkenes with N-nitrososulfonamides enabled by triplet energy transfer under neutral conditions is presented. Both (Z)- and (E)-α-amino-ketoximes are selectively accessible depending on the triplet energy of the… Click to show full abstract

An amidoximation of alkenes with N-nitrososulfonamides enabled by triplet energy transfer under neutral conditions is presented. Both (Z)- and (E)-α-amino-ketoximes are selectively accessible depending on the triplet energy of the photosensitizer.

Keywords: selective synthesis; synthesis amino; neutral conditions; amino ketoximes; controllable selective

Journal Title: Organic Chemistry Frontiers
Year Published: 2021

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