"Efficient kinetic resolution in the asymmetric transfer hydrogenation of 3-aryl-indanones: applications to a short synthesis of (+)-indatraline and a formal synthesis of (R)-tolterodine"

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Efficient kinetic resolution in the asymmetric transfer hydrogenation of 3-aryl-indanones: applications to a short synthesis of (+)-indatraline and a formal synthesis of (R)-tolterodine

Efficient kinetic resolution occurs in ATH of racemic 3-arylindanones using (R,R)-or (S,S)-Ts-DENEB catalyst and HCO2H/Et3N mixture providing near equal yields of cis-3-arylindanols and unreacted 3-arylindanones with excellent stereoselectivities. Click to show full abstract

Keywords: resolution asymmetric; kinetic resolution; asymmetric transfer; efficient kinetic; synthesis

Journal Title: RSC Advances
Year Published: 2021

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