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Sterically shielded 1,2,4-trioxolanes prepared by Griesbaum co-ozonolysis have been utilized as chemical sensors of ferrous iron in several recently described chemical probes of labile iron. Here we report optimized conditions… Click to show full abstract
Sterically shielded 1,2,4-trioxolanes prepared by Griesbaum co-ozonolysis have been utilized as chemical sensors of ferrous iron in several recently described chemical probes of labile iron. Here we report optimized conditions for co-ozonolysis that proceed efficiently and with high diastereoselectivity across an expanded range of substrates, and should enable a new generation of labile iron probes with altered reaction kinetics and physicochemical properties.
Keywords:
sensors ferrous;
ferrous iron;
expanded scope;
griesbaum ozonolysis;
iron
Journal Title: RSC Advances
Year Published: 2021
Link to full text (if available)
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Journal Title: RSC Advances
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!