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An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy… Click to show full abstract
An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)2 dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the exo-functionalized cage.
Keywords:
cage;
cage dumbbell;
dumbbell;
synthesis terpy;
terpy cage
Journal Title: RSC Advances
Year Published: 2022
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Journal Title: RSC Advances
Year Published: 2022
Link to full text (if available)
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recommendations!