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Formation and growth of lithium phosphate chemical gardens.

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We show that a chemical garden can be developed from an alkaline metal precipitate using a flow-driven setup. By injecting sodium phosphate solution into lithium chloride solution from below, a… Click to show full abstract

We show that a chemical garden can be developed from an alkaline metal precipitate using a flow-driven setup. By injecting sodium phosphate solution into lithium chloride solution from below, a liquid jet appears, on which a precipitate grows forming a structure resembling a hydrothermal vent. The precipitate column continuously builds upward until a maximum height is reached. The vertical growth then significantly slows down while the tube diameter still increases. The analysis of the growth profiles has revealed a linear dependence of volume growth rate on the injection rate, hence yielding a universal growth profile. The expansion in diameter, localized at the tip of the structure, scales with a power law suggesting that the phenomenon is controlled by both diffusion and convection.

Keywords: growth lithium; growth; lithium phosphate; phosphate chemical; lithium; formation growth

Journal Title: Soft matter
Year Published: 2022

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