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A solid-state electrolyte, Li6.4La3Zr1.4Ta0.6O12 (LLZTO), is used to block the crossover of lithium 1,2-benzenedithiolate (LBDT) in the catholyte to the lithium metal anode in a rechargeable lithium battery. The cell… Click to show full abstract
A solid-state electrolyte, Li6.4La3Zr1.4Ta0.6O12 (LLZTO), is used to block the crossover of lithium 1,2-benzenedithiolate (LBDT) in the catholyte to the lithium metal anode in a rechargeable lithium battery. The cell maintains a relatively stable cycle life (65.6% capacity retention after 100 cycles). The density functional theory simulation confirms that LBDT has strong interaction with LLZTO, which is helpful for reducing the interfacial resistance.
Keywords:
state electrolyte;
lithium;
rechargeable lithium;
solid state
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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recommendations!