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A lithiophilic/lithiophobic ternary alloy anode with Ag concentration gradients guides uniform Li deposition.

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A Li92.5Cu5Ag2.5 ternary alloy anode was designed with controlled lithiophilic/lithiophobic gradients to induce bottom-up Li deposition. The inert metal Cu served as a rigid framework that maintains structural stability, while… Click to show full abstract

A Li92.5Cu5Ag2.5 ternary alloy anode was designed with controlled lithiophilic/lithiophobic gradients to induce bottom-up Li deposition. The inert metal Cu served as a rigid framework that maintains structural stability, while the lithiophilic metal Ag provided abundant Li deposition sites. Such an ultrathin Li-rich composite anode (Li content as low as 10 mA h cm-2) affords stable cycling over 1200 h.

Keywords: anode; lithiophilic lithiophobic; deposition; alloy anode; ternary alloy

Journal Title: Chemical communications
Year Published: 2022

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