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Palladium-catalyzed rearrangement reaction to access 1-phenanthrol derivatives.

This manuscript describes an unusual Pd-catalyzed rearrangement reaction. It provides efficient access to 1-phenanthrol derivatives using allyloxy-tethered aryl iodides. This rearrangement process involves the cleavage of a C-I bond, a… Click to show full abstract

This manuscript describes an unusual Pd-catalyzed rearrangement reaction. It provides efficient access to 1-phenanthrol derivatives using allyloxy-tethered aryl iodides. This rearrangement process involves the cleavage of a C-I bond, a C-O bond and C-H bonds, and the formation of two C-C bonds in one-pot. It is likely that the key to the success of this rearrangement is via β-carbon elimination from a strained palladacycle.

Keywords: catalyzed rearrangement; access phenanthrol; phenanthrol derivatives; rearrangement reaction

Journal Title: Chemical communications
Year Published: 2022

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