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Effect of electron structure on the catalytic activity of LaCoO3 perovskite towards toluene oxidation.

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LaCoO3 perovskites with different spin states of Co3+ were prepared by calcination at 600-1000 °C. LaCoO3 with electron filling in the eg orbital at 1 exhibited a moderate interaction between… Click to show full abstract

LaCoO3 perovskites with different spin states of Co3+ were prepared by calcination at 600-1000 °C. LaCoO3 with electron filling in the eg orbital at 1 exhibited a moderate interaction between the surface oxygen, resulting in the best catalytic activity. This was verified by the O p-band center.

Keywords: effect electron; catalytic activity; structure catalytic; electron structure; electron

Journal Title: Chemical communications
Year Published: 2022

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