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Binuclear copper iodine cluster-based coordination sheets as photocatalysts for decarboxylative cyanation.

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We synthesized two new MOFs (Cu-Tpxa-1 and Cu-Tpxa-2) that were used as heterogeneous photocatalysts, combining photocatalysis and copper catalysis to achieve decarboxylative radical cyanation reactions. This new heterogeneous catalysis method… Click to show full abstract

We synthesized two new MOFs (Cu-Tpxa-1 and Cu-Tpxa-2) that were used as heterogeneous photocatalysts, combining photocatalysis and copper catalysis to achieve decarboxylative radical cyanation reactions. This new heterogeneous catalysis method optimized the redox properties and excited-state lifetimes, providing a new idea for exploring photocatalytic mechanisms.

Keywords: copper; iodine cluster; cyanation; cluster based; copper iodine; binuclear copper

Journal Title: Chemical communications
Year Published: 2022

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