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Visible light-driven CO2 reduction with a Ru polypyridyl complex bearing an N-heterocyclic carbene moiety.

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A novel Ru polypyridyl complex with an N-heterocyclic carbene ligand was successfully synthesised and characterised. The complex exhibited an intense absorption band in the visible-light region derived from the strong… Click to show full abstract

A novel Ru polypyridyl complex with an N-heterocyclic carbene ligand was successfully synthesised and characterised. The complex exhibited an intense absorption band in the visible-light region derived from the strong electron-donating character of the carbene ligand, and efficiently catalysed the visible light-driven CO2 reduction with the reaction rate of 36.7 h-1.

Keywords: polypyridyl complex; light driven; driven co2; visible light; carbene; heterocyclic carbene

Journal Title: Chemical communications
Year Published: 2022

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