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The first trivalent and pentavalent tricarbabismatranes were synthesized by the reaction of N(CH2{2-LiC6H4})3 with BiCl3 and subsequent reaction with XeF2, respectively. The trivalent bismatrane was easily oxidized by air, while… Click to show full abstract
The first trivalent and pentavalent tricarbabismatranes were synthesized by the reaction of N(CH2{2-LiC6H4})3 with BiCl3 and subsequent reaction with XeF2, respectively. The trivalent bismatrane was easily oxidized by air, while the pentavalent bismatrane difluoride was relatively stable to air. A similar pentavalent bismatrance dichloride was prone to C-Cl bond reductive elimination even at room temperature.
Keywords:
trivalent pentavalent;
properties trivalent;
pentavalent tricarbabismatranes;
synthesis structure;
structure properties;
pentavalent
Journal Title: Chemical communications
Year Published: 2022
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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recommendations!