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The fluctuating standard potential of lithium in organic solvents.

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The standard potential of a lithium metal electrode versus the standard hydrogen electrode was calculated by constructing the thermodynamic cycle in a hypothetical electrochemical cell with a dual-phase electrolyte. It… Click to show full abstract

The standard potential of a lithium metal electrode versus the standard hydrogen electrode was calculated by constructing the thermodynamic cycle in a hypothetical electrochemical cell with a dual-phase electrolyte. It is demonstrated that the standard potential of the lithium metal electrode can fluctuate over 0.5 V in different organic solvents, and is correlated to the modified donor number by the entropy of fusion of the solvents.

Keywords: standard potential; lithium organic; fluctuating standard; potential lithium; organic solvents

Journal Title: Chemical communications
Year Published: 2022

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