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A new Ag36 nanocluster with a closed electronic structure and eight valence electrons is reported, which has a similar structure to that of an open-shell Ag34 nanocluster with three valence… Click to show full abstract
A new Ag36 nanocluster with a closed electronic structure and eight valence electrons is reported, which has a similar structure to that of an open-shell Ag34 nanocluster with three valence electrons, except that in the shell two (Ag-PPh3)+ cations replace two S2- anions specifically. The fine structural modulation leads to various levels of activity for singlet oxygen photogeneration due to the distinct optical gaps of the nanoclusters.
Keywords:
metal replacement;
specific sulfur;
sulfur metal;
replacement silver;
site specific;
nanocluster
Journal Title: Chemical communications
Year Published: 2022
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!