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Fluorescence sensing of nitrophenol explosives using a two-dimensional organic-metal chalcogenide fully covered with functional groups.

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A new 2D fluorescent organic-metal chalcogenide (OMC), CdClHT (HT = 4-hydroxythiophenol), evenly covered with phenol groups is reported. CdClHT represents unparalleled selectivity and the highest sensitivity towards 2,4,6-trinitrophenol (TNP) (KSV… Click to show full abstract

A new 2D fluorescent organic-metal chalcogenide (OMC), CdClHT (HT = 4-hydroxythiophenol), evenly covered with phenol groups is reported. CdClHT represents unparalleled selectivity and the highest sensitivity towards 2,4,6-trinitrophenol (TNP) (KSV = 2.16 × 107 m-1, experimental LOD = 2 nM), among all reported 2D conjugated polymer (CP) luminescent detectors.

Keywords: fluorescence sensing; sensing nitrophenol; metal chalcogenide; organic metal

Journal Title: Chemical communications
Year Published: 2022

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