The exploration of macrocycle-based nonporous adaptive crystals (NACs) for adsorption and separation has been one of the hotspots in supramolecular chemistry and crystal engineering. Herein, we developed calix[3]acridan-based NACs to… Click to show full abstract
The exploration of macrocycle-based nonporous adaptive crystals (NACs) for adsorption and separation has been one of the hotspots in supramolecular chemistry and crystal engineering. Herein, we developed calix[3]acridan-based NACs to separate industrially important 4-picoline from its isomer mixtures with over 93.8% purity.
               
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