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Hundred-gram scale fabrication of few-layered silicene by a continuous vapor-dealloying strategy for high-performance lithium storage.

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A continuous vapor de-alloying strategy for a hundred-gram scale fabrication of silicene is developed by etching CaSi2 using waste polyvinyl chloride (PVC). The as-obtained few-layered silicene can be readily assembled… Click to show full abstract

A continuous vapor de-alloying strategy for a hundred-gram scale fabrication of silicene is developed by etching CaSi2 using waste polyvinyl chloride (PVC). The as-obtained few-layered silicene can be readily assembled with carbon nanotubes into flexible electrodes for lithium storage with excellent performance, which stably deliver a high capacity and stability. This strategy can be extended to other silicon analogs with various structures by selecting precursors such as Mg2Si and Al/Si alloy.

Keywords: hundred gram; layered silicene; gram scale; scale fabrication; continuous vapor; strategy

Journal Title: Chemical communications
Year Published: 2022

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