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Application of a chemical clock in material design: chemically programmed synthesis of zeolitic imidazole framework-8.

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Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance… Click to show full abstract

Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance of the ZIF-8 can be adjusted by the initial concentration of one reagent of the chemical clock. The autonomously synthesized ZIF-8 showed excellent morphology and crystallinity.

Keywords: synthesis zeolitic; imidazole framework; clock; zeolitic imidazole; chemical clock

Journal Title: Chemical communications
Year Published: 2022

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