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Sb-Doped high-voltage LiCoO2 enabled improved structural stability and rate capability for high-performance Li-ion batteries.

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Sb-Doped high-voltage LiCoO2 was developed with unique properties. In situ X-ray diffraction and density functional theory reveal that the introduction of Sb helps to shorten the Li+ diffusion distance, increase… Click to show full abstract

Sb-Doped high-voltage LiCoO2 was developed with unique properties. In situ X-ray diffraction and density functional theory reveal that the introduction of Sb helps to shorten the Li+ diffusion distance, increase the lattice spacing and keep the structural stability during deep lithiation, thus resulting in improved rate capability and cycling performance.

Keywords: voltage licoo2; high voltage; doped high; structural stability; rate capability

Journal Title: Chemical communications
Year Published: 2022

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