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Zero-dimensional hybrid binuclear manganese chloride with thermally stable yellow emission.

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Photoluminescence (PL) thermal quenching of hybrid metal halides blocks their applications. Herein, a novel type of 0D hybrid metal halide, [Pb(C12H24O6)Cl]2[Mn2Cl6], with broad yellow emission and near-unity PL quantum yield… Click to show full abstract

Photoluminescence (PL) thermal quenching of hybrid metal halides blocks their applications. Herein, a novel type of 0D hybrid metal halide, [Pb(C12H24O6)Cl]2[Mn2Cl6], with broad yellow emission and near-unity PL quantum yield is reported. Importantly, it preserves outstanding thermal stability up to 450 K.

Keywords: binuclear manganese; dimensional hybrid; emission; yellow emission; hybrid binuclear; zero dimensional

Journal Title: Chemical communications
Year Published: 2022

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