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We developed a strategy for manipulating the binding strength of polycyclic aromatic hydrocarbons (PAHs) via covalent post-assembly modification (PAM) of tetranuclear ruthenium macrocycles containing s-tetrazine ligands. The macrocycles act as… Click to show full abstract
We developed a strategy for manipulating the binding strength of polycyclic aromatic hydrocarbons (PAHs) via covalent post-assembly modification (PAM) of tetranuclear ruthenium macrocycles containing s-tetrazine ligands. The macrocycles act as efficient receptors for various PAHs. Inverse electron demand Diels-Alder (IEDDA) reaction of the macrocycles was applied to reduce the binding ability significantly.
Keywords:
polycyclic aromatic;
aromatic hydrocarbons;
assembly modification;
post assembly
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!