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Heterostructures of Cu2-xS/Cu2-xTe plasmonic semiconductors: disappearing and reappearing LSPR with anion exchange.

Localized surface plasmon resonance (LSPR) of Cu2-xS nanorods is quenched during the initial Cu2-xS/Cu2-xTe core/shell stage of anion exchange then returns as Cu2-xTe progresses into the nanorod. Phase change within… Click to show full abstract

Localized surface plasmon resonance (LSPR) of Cu2-xS nanorods is quenched during the initial Cu2-xS/Cu2-xTe core/shell stage of anion exchange then returns as Cu2-xTe progresses into the nanorod. Phase change within the core accounts for this behaviour illustrating the complexity emergent from anion exchange.

Keywords: anion exchange; cu2 xte; cu2; cu2 cu2

Journal Title: Chemical communications
Year Published: 2022

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