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High quantum yield photochemical water oxidation using a water-soluble cobalt phthalocyanine as a homogenous catalyst.

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We demonstrated high catalytic activity (TON = 670, TOFmax = 2.7 s-1) of a water-soluble cobalt phthalocyanine complex (CoPcTS, PcTS = phthalocyaninetetrasulfonate) for visible light-driven photochemical water oxidation and investigated… Click to show full abstract

We demonstrated high catalytic activity (TON = 670, TOFmax = 2.7 s-1) of a water-soluble cobalt phthalocyanine complex (CoPcTS, PcTS = phthalocyaninetetrasulfonate) for visible light-driven photochemical water oxidation and investigated its reaction mechanism by electrochemical and spectroscopic measurements.

Keywords: water oxidation; water; water soluble; photochemical water; soluble cobalt; cobalt phthalocyanine

Journal Title: Chemical communications
Year Published: 2022

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