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Robust formation of discrete non-covalent pyrene dimers in an amorphous film by strong π-π interaction.

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A pyrene-based non-covalent dimer in a crystal showed a strengthened π-π interaction, which was robust enough against external disturbances. Such a strong π-π interaction made the pyrene-based dimer easily form… Click to show full abstract

A pyrene-based non-covalent dimer in a crystal showed a strengthened π-π interaction, which was robust enough against external disturbances. Such a strong π-π interaction made the pyrene-based dimer easily form in the amorphous film, indicating that the dimer could potentially work as the monomer.

Keywords: interaction; strong interaction; non covalent; amorphous film; pyrene

Journal Title: Chemical communications
Year Published: 2022

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