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A simple and versatile synthesis strategy of hollow MOFs for CO2 separation and catalysis.

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A novel single-solvent-interfacial strategy is proposed to synthesize hollow MOFs, fabricated at the two-phase interface originated from the self-deliquescence of hydration water in the metallic precursors and the solvents with… Click to show full abstract

A novel single-solvent-interfacial strategy is proposed to synthesize hollow MOFs, fabricated at the two-phase interface originated from the self-deliquescence of hydration water in the metallic precursors and the solvents with low water solubility. The as-fabricated HMOFs with hierarchically porous structures exhibit significant enhancement in CO2 separation and catalysis.

Keywords: strategy; hollow mofs; co2 separation; separation catalysis

Journal Title: Chemical communications
Year Published: 2022

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