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A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing a metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10-3 S·cm-1 at 25 °C and 95%… Click to show full abstract
A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing a metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10-3 S·cm-1 at 25 °C and 95% RH, a photothermal effect over a wide spectral range from UV-vis to NIR, and photo-enhanced and switchable proton conductivity.
Keywords:
proton conduction;
photothermal effect;
conduction based;
photoresponsive proton;
proton
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!