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Photochromic and electrochromic properties of a viologen-based multifunctional Cd-MOF.

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A pair of novel multifunctional MOF materials [Cd2(L)2(D/L-Lm)(H2O)2]·5H2O (denoted as D/L-Cd-MOF) has been synthesized by combining the viologen-functionalized ligand H2L+Cl- and chiral D/L-tartaric acid (H2Lm) with a simple solvothermal method.… Click to show full abstract

A pair of novel multifunctional MOF materials [Cd2(L)2(D/L-Lm)(H2O)2]·5H2O (denoted as D/L-Cd-MOF) has been synthesized by combining the viologen-functionalized ligand H2L+Cl- and chiral D/L-tartaric acid (H2Lm) with a simple solvothermal method. Due to the unique photoelectric response properties of the viologen units, reversible photochromic and electrochromic properties have been combined in D/L-Cd-MOF, which points to a new way of designing and constructing multifunctional photoelectric materials.

Keywords: viologen based; multifunctional mof; based multifunctional; properties viologen; electrochromic properties; photochromic electrochromic

Journal Title: Chemical communications
Year Published: 2022

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