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A tin porphyrin axially-coordinated two-dimensional covalent organic polymer for efficient hydrogen evolution.

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Herein, we demonstrate a facile strategy for constructing an efficient and stable hydrogen evolution reaction (HER) catalyst, i.e. a tin porphyrin axially-coordinated 2D covalent organic polymer (SnTPPCOP). SnTPPCOP exhibits promising… Click to show full abstract

Herein, we demonstrate a facile strategy for constructing an efficient and stable hydrogen evolution reaction (HER) catalyst, i.e. a tin porphyrin axially-coordinated 2D covalent organic polymer (SnTPPCOP). SnTPPCOP exhibits promising HER activity with a low overpotential of 147 mV at 10 mA cm-2 due to its unique structural properties, ranking among the best records reported recently.

Keywords: organic polymer; covalent organic; tin porphyrin; axially coordinated; hydrogen evolution; porphyrin axially

Journal Title: Chemical communications
Year Published: 2022

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