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Bridged eosin Y: a visible and near-infrared photoredox catalyst.

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Herein, a new NIR photoredox catalyst, bridged eosin Y (BEY), has been developed. Its detailed structure and NIR optical properties are clarified by using various spectroscopic methods, X-ray single-crystal structure… Click to show full abstract

Herein, a new NIR photoredox catalyst, bridged eosin Y (BEY), has been developed. Its detailed structure and NIR optical properties are clarified by using various spectroscopic methods, X-ray single-crystal structure analysis and DFT calculations. In addition, we demonstrate the photoreaction in colored reagents and high-concentration suspensions to show the advantage of NIR photoredox-catalyzed reactions.

Keywords: eosin visible; photoredox; bridged eosin; photoredox catalyst; catalyst bridged

Journal Title: Chemical communications
Year Published: 2022

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