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Au@RhPd ultrathin nanowires are designed as a highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulate the electronic state of Rh atoms to… Click to show full abstract
Au@RhPd ultrathin nanowires are designed as a highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulate the electronic state of Rh atoms to enhance the adsorption of phenol and desorption of cyclohexanone. Pd works as a cocatalyst to activate H2 to H* and spillover to Rh sites. This new catalyst shows a turnover frequency of up to 560 h-1 for a wide spectrum of phenols with >80% selectivity toward cyclohexanones.
Keywords:
bimetallic effect;
hydrogenation;
hydrogenation phenol;
effect promotes;
promotes activity
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!