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Two-photon, red light uncaging of alkyl radicals from organorhodium(III) phthalocyanine complexes.

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A stepwise two-photon, red light excitation of organorhodium(III) phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the… Click to show full abstract

A stepwise two-photon, red light excitation of organorhodium(III) phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the photouncaging reaction and the photochemical generation of reactive oxygen species were indicated to induce the cell deaths.

Keywords: phthalocyanine complexes; two photon; red light; photon red; organorhodium iii; iii phthalocyanine

Journal Title: Chemical communications
Year Published: 2022

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