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Dramatic emission enhancement of aggregation-induced emission luminogens by dynamic metal coordination bonds and the anti-heavy-atom effect.

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Restriction of intramolecular motions of AIEgens is greatly intensified by introducing dynamic metal coordination bonds to achieve dramatic fluorescence enhancement, which provides a simple and effective way to dramatically improve… Click to show full abstract

Restriction of intramolecular motions of AIEgens is greatly intensified by introducing dynamic metal coordination bonds to achieve dramatic fluorescence enhancement, which provides a simple and effective way to dramatically improve the emission efficiency of AIEgens. AIEgen-based metal complexes have an abnormal anti-heavy-atom effect, which contributes to their high emission efficiencies without changing their emission nature.

Keywords: metal coordination; anti heavy; emission; dynamic metal; coordination bonds; heavy atom

Journal Title: Chemical communications
Year Published: 2022

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