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Fluoride-free synthesis of high-silica CHA-type aluminosilicates by seed-assisted aging treatment for starting gel.

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High-silica CHA-type aluminosilicates (Si/Al molar ratio >100) were synthesized hydrothermally in the absence of fluoride media, where the seed-assisted aging treatment played an important role on the crystallization. These aluminosilicates… Click to show full abstract

High-silica CHA-type aluminosilicates (Si/Al molar ratio >100) were synthesized hydrothermally in the absence of fluoride media, where the seed-assisted aging treatment played an important role on the crystallization. These aluminosilicates showed a long catalytic lifetime with high selectivity toward lower olefins in the methanol-to-olefins reaction.

Keywords: type aluminosilicates; high silica; silica cha; seed; cha type; seed assisted

Journal Title: Chemical communications
Year Published: 2022

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