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Luminescent magnesium complexes with intra- and inter-ligand charge transfer.

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Herein, we report two 2,2'-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively.… Click to show full abstract

Herein, we report two 2,2'-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer.

Keywords: inter ligand; ligand; magnesium complexes; ligand charge; intra inter; charge transfer

Journal Title: Chemical communications
Year Published: 2022

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