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Herein, we describe a protocol for the direct and selective acylation and alkynylation of the C(sp3)-H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. This method, using… Click to show full abstract
Herein, we describe a protocol for the direct and selective acylation and alkynylation of the C(sp3)-H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. This method, using cheap and easy-to-synthesize TBADT as a HAT photocatalyst, exhibits excellent site selectivity. A wide variety of high-value ketones, amides, esters, and diverse alkynes can be efficiently constructed from abundant hydrocarbon feedstocks.
Keywords:
decatungstate photo;
synergistic decatungstate;
nickel catalysis;
hat nickel;
photo hat;
acylation alkynylation
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!