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The catalytic synthesis of silylamines mediated by s- and p-block catalysts is largely underdeveloped. Herein, commercially available potassium bis(trimethylsilyl)amide serves as an efficient alternative to transition metal complexes. N-H/Si-C dealkynative… Click to show full abstract
The catalytic synthesis of silylamines mediated by s- and p-block catalysts is largely underdeveloped. Herein, commercially available potassium bis(trimethylsilyl)amide serves as an efficient alternative to transition metal complexes. N-H/Si-C dealkynative coupling was achieved by means of user-friendly main-group catalysis with ample substrate scope and high chemoselectivity.
Keywords:
formation via;
nitrogen bond;
dealkynative coupling;
bis trimethylsilyl;
silicon nitrogen;
bond formation
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!