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Kinetically controlled narcissistic self-sorting of Pd(II)-linked self-assemblies from structurally similar tritopic ligands.

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Herein, we present the narcissistic self-sorted state from two kinds of structurally similar tritopic ligands with a cis-protected Pd(II) complex, which was generated by both the pathway-dependent process and the… Click to show full abstract

Herein, we present the narcissistic self-sorted state from two kinds of structurally similar tritopic ligands with a cis-protected Pd(II) complex, which was generated by both the pathway-dependent process and the proper choice of the leaving ligand. This metastable state could not be attained by simple mixing of all components by heating under thermodynamic control.

Keywords: similar tritopic; tritopic ligands; narcissistic self; structurally similar

Journal Title: Chemical communications
Year Published: 2022

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