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Light-switched selective catalysis with NADH mimic functionalized metal-organic capsules.

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By incorporating an active site model of nicotinamide adenine dinucleotide (NADH) as an electron regulator, a redox-active metal-organic capsule as an efficient photocatalyst was obtained for the light switchable synthesis… Click to show full abstract

By incorporating an active site model of nicotinamide adenine dinucleotide (NADH) as an electron regulator, a redox-active metal-organic capsule as an efficient photocatalyst was obtained for the light switchable synthesis of a series of aromatic azoxy and amino compounds from their corresponding nitroaromatics under either purple (420 nm) or blue (455 nm) LED light irradiation.

Keywords: light switched; selective catalysis; switched selective; metal organic; metal; catalysis nadh

Journal Title: Chemical communications
Year Published: 2022

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