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The template effect of a SiF62- guest drives the formation of a heteroleptic Fe(II) coordination helicate.

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The anion SiF62- exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within… Click to show full abstract

The anion SiF62- exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.

Keywords: coordination; effect sif62; sif62; template effect; helicate

Journal Title: Chemical communications
Year Published: 2022

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