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A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex.

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The synthesis and characterisation of [Co2(η4-P2C2tBu2)2(μ:η4:η4-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands. Click to show full abstract

The synthesis and characterisation of [Co2(η4-P2C2tBu2)2(μ:η4:η4-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands.

Keywords: diphosphacyclobutadiene tripledecker; tris diphosphacyclobutadiene; sandwich complex; diphosphacyclobutadiene; homoleptic tris

Journal Title: Chemical communications
Year Published: 2022

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