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Spatially confined magnesiothermic reduction induced uniform mesoporous hollow silicon carbide nanospheres for high-performance supercapacitors.

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In this work, mesoporous hollow SiC nanospheres (MHS-SiC) are successfully fabricated via in situ magnesiothermic reduction of mesoporous hollow carbon-silica nanospheres (MHS-SiO2/C), which inherit a unique interconnected network on the… Click to show full abstract

In this work, mesoporous hollow SiC nanospheres (MHS-SiC) are successfully fabricated via in situ magnesiothermic reduction of mesoporous hollow carbon-silica nanospheres (MHS-SiO2/C), which inherit a unique interconnected network on the shell. The specially designed interpenetrating shell structure provides an accessible interface between Si and C elements in a confined nanospace during magnesiothermic reduction, and thus well-dispersed MHS-SiC nanospheres (∼95 nm in diameter) with interconnected mesoporous shells and high specific surface area (868 m2 g-1) can be obtained. For practical applications, the obtained MHS-SiC electrode exhibits a high-rate capacitance and long cycling stability for supercapacitors.

Keywords: spatially confined; mhs sic; magnesiothermic reduction; mesoporous hollow

Journal Title: Chemical communications
Year Published: 2022

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