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In situ lead oxysalt passivation layer for stable and efficient perovskite solar cells.

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A Rb2SO4 additive is employed to passivate the Pb2+ defects in a perovskite film by forming PbSO4in situ, which can cover the surface and grain boundaries of the perovskite to… Click to show full abstract

A Rb2SO4 additive is employed to passivate the Pb2+ defects in a perovskite film by forming PbSO4in situ, which can cover the surface and grain boundaries of the perovskite to ensure that the film is not decomposed by moisture. Finally, a device based on the Rb2SO4 modification achieved an enhanced power conversion efficiency (22.25%) and long-term stability.

Keywords: stable efficient; situ lead; passivation layer; lead oxysalt; layer stable; oxysalt passivation

Journal Title: Chemical communications
Year Published: 2022

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