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Visible-light driven reaction of CO2 with alcohols using a Ag/CeO2 nanocomposite: first photochemical synthesis of linear carbonates under mild conditions.

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The first photochemical synthesis of linear carbonates from the reaction of CO2 with alcohols using a silver-doped ceria nanocomposite at room temperature under visible light irradiation is described. DFT calculations… Click to show full abstract

The first photochemical synthesis of linear carbonates from the reaction of CO2 with alcohols using a silver-doped ceria nanocomposite at room temperature under visible light irradiation is described. DFT calculations suggested the electron transfer from Ag 4d states to Ce 4f states in the composite for the photoreaction.

Keywords: linear carbonates; synthesis linear; reaction co2; photochemical synthesis; first photochemical; co2 alcohols

Journal Title: Chemical communications
Year Published: 2023

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