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The synthesis and structures of the homoleptic hexanitrato complexes of Am(III) and Cm(III), [(CH3)4N]2KAn(NO3)6 are reported. These compounds form a double perovskite structure type, A2B'BX6, crystallizing in the cubic space… Click to show full abstract
The synthesis and structures of the homoleptic hexanitrato complexes of Am(III) and Cm(III), [(CH3)4N]2KAn(NO3)6 are reported. These compounds form a double perovskite structure type, A2B'BX6, crystallizing in the cubic space group Fm3̄m. Their electronic properties, as calculated using the Quantum Theory of Atoms in Molecules, are reported and compared to their lanthanide homologues Eu(III) and Gd(III).
Keywords:
am3 cm3;
hexanitrato complexes;
hybrid double;
complexes hybrid;
double perovskites;
perovskites am3
Journal Title: Chemical communications
Year Published: 2022
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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recommendations!